Surface modification and characterization of carbon spheres by grafting polyelectrolyte brushes

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Surface modification and characterization of carbon spheres by grafting polyelectrolyte brushes

Modified carbon spheres (CSPBs) were obtained by grafting poly(diallyl dimethyl ammonium chloride) (p-DMDAAC) on the surface of carbon spheres (CSs). It can be viewed as a kind of cation spherical polyelectrolyte brushes (CSPBs), which consist of carbon spheres as core and polyelectrolytes as shell. The method of synthesizing carbon spheres was hydrothermal reaction. Before the polyelectrolyte ...

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Modification of Silica surface by Titanium sol synthesis and characterization

Hydrophobic silica titanium nanoparticles (STNPs) were successfully synthesized by the sol-gel process using liquid modification. Fourier transform infrared (FTIR) and X-ray fluorescence (XRF) studies were demonstrated the attachment of titanium on the silica surface. Titanium content enhanced the agglomeration of particles as shown in topography results. The N2 adsorption-desorption followed T...

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Lubrication by Polyelectrolyte Brushes

We develop a scaling model relating the friction forces between two polyelectrolyte brushes sliding over each other to the separation between grafted surfaces, number of monomers and charges per chain, grafting density of chains, and solvent quality. We demonstrate that the lateral force between brushes increases upon compression, but to a lesser extent than the normal force. The shear stress a...

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Formation and Characterization of Covalently Bound Polyelectrolyte Brushes

Poly(4-vinylpyridine) (PVP), functionalized at one terminus with a styrenyl group, was end-grafted to vinyl-functionalized self-assembled monolayers by UV irradiation in 1-methyl-2-pyrrolidinone. In this solvent and with oxygen excluded, surface reactions appeared to be selectively limited to the polymer terminus. The dry film thickness was determined by ellipsometry and the grafted amount by F...

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ژورنال

عنوان ژورنال: Nanoscale Research Letters

سال: 2014

ISSN: 1556-276X

DOI: 10.1186/1556-276x-9-283